Triaqua(2-{[(E)-5-formyl-2-oxidobenzylidene]amino}ethanesulfonato)cobalt(II) dihydrate
نویسندگان
چکیده
The title compound, [Co(C(10)H(9)NO(5)S)(H(2)O)(3)]·2H(2)O, is a cobalt-Schiff base complex derived from taurine. There are two complex mol-ecules and four solvent water mol-ecules in the asymmetric unit. The central Co atom is six coordinated by two O atoms and one N atom of the ligand and three O atoms of water mol-ecules, forming a slightly distorted octa-hedral geometry. The crystal structure is stabilized by several O-H⋯O hydrogen bonds.
منابع مشابه
{2-[(5-Bromo-2-oxidobenzylidene)amino-κ2 N,O]-3-methylpentanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
In the title compound, [Cu(C(13)H(14)BrNO(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is penta-coordinated in a square-pyramidal geometry. The crystal packing is stabilized by O-H⋯O hydrogen bonds.
متن کامل{2-(4-Hydroxyphenyl)-2-[(3-methoxy-2-oxidobenzylidene)amino-κ2 O 2,N]propanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
In the title complex, [Cu(C(17)H(15)NO(5))(C(12)H(8)N(2))]·2H(2)O, the central Cu(II) ion is five-coordinate, bound to one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal configuration. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds form a two-dimensional network parallel to (001).
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متن کاملHexaaquacobalt(II) tetraaquabis(2-aminopyrazine-κN 4)cobalt(II) disulfate dihydrate
The reaction of cobalt(II) sulfate and 2-amino-pyrazine affords the title salt, [Co(H(2)O)(6)][Co(C(4)H(5)N(3))(2)(H(2)O)(4)](SO(4))(2)·2H(2)O. The metal atoms in the tetra-aqua-coordinated and hexa-aqua-coordinated complex cations lie on centers of inversion in slightly distorted octa-hedral geometries. The cations, anions and solvent water mol-ecules are linked by O-H⋯O, O-H⋯N and N-H⋯O hydro...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009